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Temperature dependent Kirkwood-Buff parameters G p p , G w w and G p w have been evaluated for the 1-propanol-water solution (1:5 in mole ratio) from S c c (0) obtained by small angle neutron scattering (SANS) experiments. Structural model for the concentration fluctuation for the solution at 25°C has been constructed based on the value of G p p . Characteristic feature of the SANS intensity and fractal nature of the concentration fluctuation can be explained qualitatively by the model structure. The volume fraction w of propanol-rich regions in the solution has been estimated as a function of temperature. Salt-induced phase separation phenomena observed on the current solution is discussed based on the temperature-dependent percolation theory.
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Misawa et al. (2000) studied this question.
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