Thermal dehydrochlorination of poly(vinyl chloride) was demonstrated to be capable of being maximally inhibited by triphenylmethane. Arrhenius parameters observed under conditions of full inhibition are consistent with a unimolecular loss of hydrogen chloride occurring concurrently with a radical‐chain process. At 194°C, the rate of the molecular process is about 30% of the overall reaction, but at higher temperatures it becomes the predominant pathway.
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Nolan et al. (1976) studied this question.
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