Hydrothermal Synthesis and Characterization of Novel One-Dimensional Tellurites of Molybdenum(VI), A₄Mo₆TeO₂₂·2H₂O (A = NH₄, Rb)

Two novel, isostructural, one-dimensional tellurites of molybdenum(VI), (NH 4 ) 4 Mo 6 TeO 22 ·2H 2 O and Rb 4 Mo 6 TeO 22 ·2H 2 O, have been synthesized by hydrothermal method. They contain linear (Mo 6 TeO 22 ) 4 - anionic chains, parallel to one another and held together by NH 4 + /Rb + ions. “Mo 6 O 22 ” moieties, formed by edge-sharing of six MoO 6 octahedra, are connected through tellurium resulting in the (Mo 6 TeO 22 ) 4 - anionic chain. Tellurium is four-coordinated with SF 4 geometry. The water of crystallization occupies the rest of the lattice. Both compounds have been structurally characterized by single-crystal X-ray diffraction studies. Pertinent crystal data are as follows: for (NH 4 ) 4 Mo 6 TeO 22 ·2H 2 O, monoclinic space group C 2/ c, a = 21.354(10) Å, b = 7.761(2) Å, c = 15.508(10) Å, β = 119.34(5)°, Z = 4; for Rb 4 Mo 6 TeO 22 ·2H 2 O, monoclinic space group C 2/ c, a = 21.410(5) Å, b = 7.757(2) Å, c = 15.507(7) Å, β = 119.68(3)°, Z = 4. Hydrothermal syntheses, structure, powder X-ray diffraction, spectroscopy, and thermal studies of these compounds are described.