We demonstrate cooling of calcium atoms using a two-photon transition from the ¹S₀ ground state to the upper 4s5s3.33333pt0ex¹S₀ state via the ¹P₁ intermediate state. We achieve temperatures as low as 2600.16em0exK in a magnetooptical trap (MOT), well below the Doppler limit (TD=0.80.16em0exmK) of the ¹P₁ state. We characterize the temperature, lifetime, and confinement of the MOT over a range of experimental parameters, observing no reduction in lifetime due to coupling to the higher state. We perform theoretical simulations of the cooling scheme and observe good agreement with the experimental results. The two-photon cooling scheme presented in this work provides an alternative to the standard Doppler cooling applied to alkaline-earth atoms, based on a sequence of two magnetooptical traps. The advantages of our scheme are the possibility of varying the effective linewidth of the ¹P₁ state, a higher transfer efficiency (close to $100%$), and a more straightforward experimental implementation.
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Adamczyk et al. (2025) studied this question.
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