All articles of this category We synthesized a new type of antiferroelectric and ferroelectric liquid-crystalline molecules with double stereogenic centers based on the binaphthol-titanium complex-catalyzed fluoral-ene reaction with vinyl sulfides. Furthermore, we experimentally showed the importance of the diastereomer effect for the appearance of the antiferroelectric SmC A * phase. Fluoral-ene reaction - Binaphthol-titanium complex - α-Trifluoromethyl-β-methyl carbinols - Antiferroelectric liquid-crystals - Vinyl sulfides
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Mikami et al. (1996) studied this question.
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