Ru and Ir catalysts, which are not particularly selective under the conditions of conventional hydrogenation carried out with molecular hydrogen, when used in the Aqueous-Phase Reforming/Hydrogenation (APR/Hyd) process, become >99.9% selective for hydrogenation of o-chloronitrobenzene to o-chloraniline.
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Mariusz Pietrowski (2011) studied this question.
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