In the system LiI — ZnI 2 , the hitherto unknown peritectically melting Li 2 ZnI 4 has been established. It crystallizes in the olivine structure (a = 1480.3(9), b = 856.0(2), and c = 701.2(1) pm) and exhibits high ionic conductivity. Thermoanalytical and Raman spectroscopic data are included.
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Lutz et al. (1989) studied this question.