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While Cs2O-coated III-V semiconductors can have Kelvin work functions as low as 0.7 eV, the long-wavelength threshold for efficient photoemission is determined by a significantly higher barrier at the heterojunction between the Cs2O and the semiconductor. This barrier is 1.23±0.03 eV for Cs2O on GaSb. For Cs2O on silver, the barrier height is 1.0 eV.
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James et al. (1970) studied this question.
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