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February 9, 2006Angewandte Chemie

Photoswitching of the Dielectric Constant of the Spin‐Crossover Complex [Fe(L)(CN)₂]⋅H₂O

Sébastien Bonhommeau Thomas Guillon Latévi Max Lawson Daku Philippe Demont José Sánchez Costa Jean‐François Létard Gábor Molnár Azzedine Bousseksou

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Abstract

Photochemisches Schalten der Dielektrizitätskonstante trifft man erstmalig in dem Spin-Crossover-Komplex [Fe(L)(CN)2]⋅H2O an (siehe Bild; L=2,13-Dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaen). Die elektrische Detektion des photoinduzierten Wechsels des Spinzustands lässt derartige Komplexe für optische Informationsspeicher interessant erscheinen.

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Cite This Study

Bonhommeau et al. (2006) studied this question.

synapsesocial.com/papers/6a82f35fee90e576a3af7fc3 https://doi.org/10.1002/ange.200503252

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Spin-Transition Polymers: From Molecular Materials Toward Memory DevicesOriginal Research · 1998 · 2,274 citations
2Nanoscale Science of Single Molecules Using Local ProbesOriginal Research · 1999 · 679 citations
3Thermal and Optical Switching of Iron(<scp>II</scp>) ComplexesOriginal Research · 1994 · 2,145 citations
4One Shot Laser Pulse Induced Reversible Spin Transition in the Spin‐Crossover Complex [Fe(C<sub>4</sub>H<sub>4</sub>N<sub>2</sub>){Pt(CN)<sub>4</sub>}] at Room TemperatureOriginal Research · 2005 · 92 citations
5One Shot Laser Pulse Induced Reversible Spin Transition in the Spin‐Crossover Complex [Fe(C<sub>4</sub>H<sub>4</sub>N<sub>2</sub>){Pt(CN)<sub>4</sub>}] at Room TemperatureOriginal Research · 2005 · 332 citations

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