Unprecedented kinetic resolution of (±)-cyclohex-1-enylsilanols 1 by the Sharpless asymmetric epoxidation has been accomplished, the rate difference between enantiomers, krel, being >11 to give enantiomerically pure cyclohex-1-enylcyclohexylmethylsilanol 1b in a particular case.
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Yamamoto et al. (1993) studied this question.
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