An improved kinetic formula which can be used to estimate the average phonon resistive lifetime τR from thermal conductivity data is presented. The relation is {κ}=Cc₂²{{{τ}}}R, where κ is the thermal conductivity, C is the specific heat, and{c}₂$ is the second sound velocity. At very low temperatures ${c}₂{c}D/ 3 , where{c}D$ is the Debye velocity, and the result reduces to the standard kinetic formula. However, above about 0.02${FTHETA}D$ ${c}₂$ undergoes a rapid decrease. As a consequence, phonon lifetimes estimated by the modified formula are considerably longer than those obtained from the standard kinetic formula.
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Stoner et al. (1993) studied this question.
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