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This study demonstrates that the amount of discharge product (Li2O2) precipitated on the separator in a lithium oxygen cell using glyme-based electrolytes depends on the anion. The stability of the discharge intermediate (LiO2) in the electrolyte has been shown to depend on the anionic species, which is related to Li2O2 precipitation on the separator. The implications for producing an efficient and long-life Li-O2 cell are elaborated.
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Kwon et al. (2017) studied this question.
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