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Reversible addition−fragmentation chain transfer (RAFT) polymerization techniques were utilized to polymerize N -acryloyl- l -phenylalanine methyl ester ( l -Phe-OMe) and tetrahydropyranyl acrylate to afford amphiphilic star polymers (with 4 and 6 arms). These copolymer stars have a chiral hydrophobic core domain and can undergo further solution self-assembly to form well-defined nanostructures, which have been characterized using DLS, TEM, and cryo-TEM analysis. The characterization and properties of these novel chiral assemblies and their potential in racemic resolution are reported.
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Skey et al. (2010) studied this question.
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