We extend the usual static view of short range order in metallic glasses to a dynamical model of local order. We use an atomistic simulation of a NiZr glass to investigate time-dependent fluctuations of the atomic environment. We show that, even in the "frozen" glass, the solute-centered clusters change their identities between distinct polyhedron types. The frequency spectrum of these transitions exhibits a characteristic peak which we show to be related to a universal vibrational anomaly of disordered solids: the controversial boson peak.
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Guerdane et al. (2008) studied this question.
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