A novel method has been developed for the synthesis of S-alkyl(aryl) thiocarbamates. The route involves, first, the formation of zinc thiolates by reductive cleavage of disulfides in the presence of Zn/AlCl3 system; then subsequent reaction of the thiolate anions with isocyanates gives the desired thiocarbamates in high to excellent yields.
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Movassagh et al. (2005) studied this question.
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