In Situ CVD Derived Co–N–C Composite as Highly Efficient Cathode for Flexible Li–O₂ Batteries

To promote the development of high energy Li–O 2 batteries, it is important to design and construct a suitable and effective oxygen‐breathing cathode. Herein, activated cobalt‐nitrogen‐doped carbon nanotube/carbon nanofiber composites (Co‐N‐CNT/CNF) as the effective cathodes for Li–O 2 batteries are prepared by in situ chemical vapor deposition (CVD). The unique architecture of these electrodes facilitates the rapid oxygen diffusion and electrolyte penetration. Meanwhile, the nitrogen‐doped carbon nanotube/carbon nanofiber (N‐CNT/CNF) and Co/CoN x serve as reaction sites to promote the formation/decomposition of discharge product. Li–O 2 batteries with Co‐N‐CNT/CNF cathodes exhibit superior electrochemical performance in terms of a positive discharge plateau (2.81 V) and a low charge overpotential (0.61 V). Besides, Li–O 2 batteries also present a high discharge capacity (11512.4 mAh g −1 at 100 mA g −1 ), and a long cycle life (130 cycles). Meanwhile, the Co‐N‐CNT/CNF cathode also has an excellent flexibility, thus the assembled flexible battery with Co‐N‐CNT/CNF can work normally and hold a wonderful capacity rate under various bending conditions.