Highly enantioselective Michael addition of acetone to a variety of nitroalkenes promoted by simple chiral primary amine bifunctional catalysts (e.g., Noyori's Ts‐DPEN ligand) together with terephthalic acid in excellent yields (84–99 %) and enantioselectivities (93–98 % ee ) is reported.
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Peng et al. (2010) studied this question.
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