CC-linkage of two o-phenylene ligands was observed in the isomerization of the dinuclear gold(II) complex 1, X = I or Br, to 2. An unusual feature of this rearrangement is that the product remains fixed via the P-donor atoms in the coordination sphere of the metal atoms.—1 is obtained from 1a (see previous communication).
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Bennett et al. (1987) studied this question.
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