Ba2BS3Cl and Ba5B2S8Cl2 have been synthesized by using PbCl2 as the flux and source of halogen. The two compounds show 3D network structures built by isolated [BS3] units with different Ba-S-Cl groups. This work enriches the structural diversity of boron chemistry and provides an insight into the synthesis of thioborates.
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Zhou et al. (2021) studied this question.
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