The diphosphino−alane ligand ClAl[C 6 H 4 ( o -P- i -Pr 2 )] 2 ( 1 ) has been prepared and reacted with [AuCl(SMe 2 )]. X-ray analyses and DFT calculations substantiate the preference of the ensuing complex 2 for a zwitterionic structure, resulting from internal chloride abstraction by aluminum over a neutral form featuring an Au→Al interaction.
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Sircoglou et al. (2008) studied this question.
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