January 1, 2001Chemical CommunicationsOpen Access

The tetramethylpiperidinyl-1-oxide anion (TMPO–) as a ligand in lanthanide chemistry: synthesis of the per(TMPO–) complex [(ONC5H6Me4)2Sm(µ-ONC5H6Me4)]2

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Abstract

(C5Me5)3Sm reacts with the free radical 2,2,6,6-tetramethylpiperidinyl-1-oxy (TMPO) to form (C5Me5)2 and the per nitroxide [(eta 1-ONC5H6Me4)2Sm(mu-eta 1:eta 2-ONC5H6Me4)]2.

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Evans et al. (2001) studied this question.

synapsesocial.com/papers/6a83f7442b578ef1603e996b https://doi.org/10.1039/b106869p

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Abstract

(C5Me5)3Sm reacts with the free radical 2,2,6,6-tetramethylpiperidinyl-1-oxy (TMPO) to form (C5Me5)2 and the per nitroxide [(eta 1-ONC5H6Me4)2Sm(mu-eta 1:eta 2-ONC5H6Me4)]2.

The tetramethylpiperidinyl-1-oxide anion (TMPO–) as a ligand in lanthanide chemistry: synthesis of the per(TMPO–) complex [(ONC5H6Me4)2Sm(µ-ONC5H6Me4)]2

Abstract

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Cite This Study

The tetramethylpiperidinyl-1-oxide anion (TMPO–) as a ligand in lanthanide chemistry: synthesis of the per(TMPO–) complex [(ONC5H6Me4)2Sm(µ-ONC5H6Me4)]2

Abstract

Discussion

Cite This Study

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