A Fischer carbene complex within the N-heterocyclic carbene skeleton is present in MnI/AuI heterometallic compounds that were synthesized from an acyclic diaminocarbene complex, through a translocation process of metallic ions under basic conditions and subsequent alkylation with methyl triflate (see scheme; bipy=bipyridyl, [Mn]=[Mn(CO)2(bipy)]).
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Ruiz et al. (2011) studied this question.
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