The syntheses and structural characterization of a series of mononuclear bis(pyrazolyl)hydroborato thallium complexes Tl[BpButR] (R = Me, Prii, But) are described. In each case, the two-coorinate Tl(I) centers of Tl[BpBut,R] are supplemented by secondary [Tl…H-B] interactions.
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Dowling et al. (1997) studied this question.
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