The distribution of structurally characterized terminal chalcogenido complexes as a function of both the chalcogen and transition metal has been surveyed with the aid of the Cambridge Structural Database. The majority of these complexes are concentrated along the vanadium-molybdenum-rhenium diagonal with oxo derivatives being the most prevalent. Terminal chalcogenido derivatives of the early and late transition metals, and terminal tellurido complexes of all the transition metals, are particularly rare. Trends in the variation of metal-chalcogenido bond lengths are also described.
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Trnka et al. (1997) studied this question.
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