Interface Engineered WxC@WS₂ Nanostructure for Enhanced Hydrogen Evolution Catalysis

For increasing scalability and reducing cost, transition metal dichalcogenides‐based electrocatalysts presently have been proposed as substitutes for noble metals to generate hydrogen, but these alternatives usually suffer from inferior performance. Here, a Ravenala leaf‐ like W x C@WS 2 heterostructure is grown via carbonizing WS 2 nanotubes, whose outer walls being partially unzipped along with the W x C “leaf‐valves” attached to the inner tubes during the carbonization process. This heterostructure exhibits a catalytic activity for hydrogen evolution reaction with low overpotential of 146 mV at 10 mA cm −2 and Tafel slope of 61 mV per decade, outperforming the performance of WS 2 nanotubes and W x C counterparts under the same condition. Density functional theory calculations are performed to unravel the underlying mechanism, revealing that the charge distribution between W x C and WS 2 plays a key role for promoting H atom adsorption and desorption kinetics simultaneously. This work not only provides a potential low‐cost alternative for hydrogen generation but should be taken as a guide to optimize the catalyst structure and composition.