The sedimentation of a reversibly aggregating substance is discussed on the basis of a model in which diffusion is neglected, as in an earlier theory, but in which concentration dependent sedimentation coefficients are now included. In addition, the effect of non-aggregating impurities is assessed. Sedimentation velocities calculated by computer for the model have been compared with published experimental results for β-lactoglobulin A and agreement has been found between theory and experiment.
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Geoffrey A. Gilbert (1963) studied this question.
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