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Disorder induced phase slip (PS) events appearing in the current voltage characteristics (IVCs) are reported for two-dimensional TiN thin films produced by a robust substrate mediated nitridation technique. Here, high temperature annealing of Ti/Si 3 N 4 based metal/substrate assembly is the key to produce majority phase TiN accompanied by TiSi 2 & elemental Si as minority phases. The method itself introduces different level of disorder intrinsically by tuning the amount of the non-superconducting minority phases that are controlled by annealing temperature ( T a ) and the film thickness. The superconducting critical temperature ( T c ) strongly depends on T a and the maximum T c obtained from the demonstrated technique is about 4.8 K for the thickness range ~ 12 nm and above. Besides, the dynamics of IVCs get modulated by the appearance of intermediated resistive steps for decreased T a and the steps get more prominent for reduced thickness. Further, the deviation in the temperature dependent critical current ( I c ) from the Ginzburg–Landau theoretical limit varies strongly with the thickness. Finally, the T c , intermediate resistive steps in the IVCs and the depairing current are observed to alter in a similar fashion with T a and the thickness indicating the robustness of the synthesis process to fabricate disordered nitride-based superconductor.
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Yadav et al. (2021) studied this question.
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