The usual concepts of the dynamics of an overloaded solute band fail to explain several phenomena such as the typical “leading‐tail” shape and retention deviations exhibited by overloaded peaks, and why these defects are more commonly observed in short columns. These and other related deviations from theory can be rationalized by a non‐classical approach to the overloading phenomenon.
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Yabumoto et al. (1980) studied this question.
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