Organocuprates are mostly monomeric in solution! This is the result of the investigation of the aggregation behavior of reagents with the stoichiometry [R2Cu(X)Li2], carried out for the first time by cryoscopy in tetrahydrofuran. Thus, Gilman cuprates (X = I) and cyanocuprates (X = CN) may belong to the same structural type 1.
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Gerold et al. (1997) studied this question.
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