Cocrystallisation of ortho-meta- and para-carboranes with hmpa (hexamethylphosphoramide) results in the isolation of 1 : 1 carborane:hmpa adducts which provide the first definitive X-ray structures of the unsubstituted carboranes as part of three very different C–H⋯O hydrogen-bonded supramolecular structures.
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Davidson et al. (1996) studied this question.
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