The reduction of a continuous Markov process with multiple metastable states to a discrete rate process is investigated in the presence of slow time-dependent parameters such as periodic external forces or slowly fluctuating barrier heights. A quantitative criterion is provided under which condition a kinetic description with time-dependent frozen rates applies and nonadiabatic corrections to the frozen rates are obtained. Finally it is shown how the long-time behavior of the underlying continuous process can be retrieved from the knowledge of the discrete process by means of an appropriate random decoration of the discrete states. As a particular example of the presented theory an overdamped bistable Brownian oscillator with periodic driving is discussed.
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Talkner et al. (2004) studied this question.
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