The virial theorem is used to derive an exact relation between the kinetic and interaction parts of the surface energy of an electron gas. A similar result is derived within the framework of the density-functional formalism. These results are generalized to the surface energy of a d-dimensional electron gas. In four dimensions we find that the density dependence of the surface energy is of the form σ=Aρ5/4.
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Vannimenus et al. (1977) studied this question.
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