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January 1, 1972Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

Energy partition in the photolysis of HI and of H2S

G. A. Oldershaw David Porter A L S Smith

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Abstract

Yields of nitrogen from reaction (1) were used to determine the initial kinetic energy of hydrogen atoms produced by photolysis of HI and H2S in the presence of N2O. H*+ N2O → N2+ OH. (1)The results show that the proportion of excited (52P½) iodine atoms formed by photolysis of HI at 279 nm is 0.11 ± 0.14, and that 90 ± 10 % of the residual energy following photolysis of H2S at 248 nm appears in translation of H and SH.

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Oldershaw et al. (1972) studied this question.

synapsesocial.com/papers/6a8447b722c36ed33af79a17 https://doi.org/10.1039/f19726802218

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