Poly(styrene‐ co ‐ N ‐maleimide) precursor and poly(styrene‐ co ‐ N ‐maleimide)‐ block ‐polystyrene have been synthesized by quasiliving radical polymerization. Low molecular weight compounds with the sites specific for the complementary binding to the maleimide moieties via triple hydrogen bonds, 2,4‐diamino‐6‐ n ‐alkoxy(C‐4, C‐8, and C‐12)‐ s ‐triazines, have been prepared. Hydrogen bonding between diaminotriazine and maleimide units in the copolymer–diaminotriazine mixtures has been investigated by FTIR. Microphase separated structure in the block copolymer‐diaminotriazine mixtures has been confirmed by DSC.
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Krakovský et al. (2006) studied this question.
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