The pattern formation of silver electrodeposits was investigated in magnetic fields in connection with the diffusion-limited-aggregation (DLA) perturbed by rotating convection. The electrolysis was performed in a thin-layer solution with a three-electrode system, and the in situ ac impedance was measured simultaneously in order to examine the rate-determining step. It was found that the magnetic field changes a dendritic growth pattern into the DLA-like one with the change of the rate-determining step.
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Mogi et al. (1995) studied this question.
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