Vibrational energy transfer from OH (v=1, 2) to a number of simple hydrides (CH4, NH3, H2O, HCl, H2, D2) has been investigated using a discharge flow apparatus attached to a sensitive EPR spectrometer. Strong similarities between the rate of vibrational energy transfer from OH and the rate of V–V transfer from HCl have been observed. These similarities have been discussed in terms of the mechanism of the energy transfer process.
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Glass et al. (1982) studied this question.
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