Compounds with a gallium−lanthanide metal-to-metal bond, [(η 5 -C 5 Me 5 ) 2 Eu−{Ga(η 5 -C 5 Me 5 )} 2 ] and [(η 5 -C 5 Me 5 ) 2 (THF)Yb−Ga(η 5 -C 5 Me 5 )], were prepared by reacting [(η 5 -C 5 Me 5 )Ga] with the corresponding metallocenes of the lanthanides.
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Wiecko et al. (2007) studied this question.
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