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Samarium III monoalkoxides bearing two, one, or no cyclopentadienyl type spectator ligands are easily synthesized by monoelectronic oxidation with tert -butylperoxide of the corresponding samarium II precursors. These monoalkoxides are single-site initiators for ring-opening polymerization.
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Barbier‐Baudry et al. (2001) studied this question.
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