Arrhenius parameters have been determined for the addition of trichloromethyl radicals to fluoroethylenes; for the unsymmetric olefins the parameters have been determined for each end of the double bond. [graphic omitted] The determined activation energies are compared with localization energies, and with free valence as calculated from simple Hückel theory.
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Tedder et al. (1966) studied this question.
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