A ternary hybrid nucleating agent for isotropic polypropylene: Preparation, characterization, and application

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A ternary hybrid nucleating agent (THNA) powder was prepared by co-spray drying the fluid mixture of Si-MP/SNa slurry. The THNA was characterized by Fourier transform infrared and thermogravimetric analyses; the results showed that THNA was prepared successfully. The results of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed that THNA was ring-shaped or mushroom cap-shaped and it was uniformly dispersed in the iPP matrix. With the incorporation of THNA (0.2 wt%), the crystallization peak temperature of iPP/THNA increased effectively. The nucleation efficiency and crystallinity were improved to 69% and 58%, respectively. Moreover, the flexural strength, flexural modulus, tensile strength, and impact toughness of iPP/THAN were enhanced to 49.3 MPa, 1,988 MPa, 42 MPa, and 4.93 kJ·m −2 , respectively. The transparency was increased to 77.7%, and the haze was reduced to 14.1%. The compound of sodium laurate and inorganic silica/aromatic phosphate had an obvious synergistic effect.