Multichip module (MCM) structures were used to study the reliability of copper conductors embedded in polyimide. Conductor lines fully encased in titanium passivation, 50-100 nm thick, increased in resistance less than 0.4% after 1000 h of exposure to 85% humidity at 85 degrees C and 10-V bias. The fully encased lines also had corrosion rates six times lower than lines that had only 60% passivation coverage. Transmission lines passivated with 50 nm of titanium showed very little degradation in the rise time or amplitude of digital pulses that had a 0.5-GHz clock rate and 149-ps rise time. Copper/polyimide via chain structures were fabricated from vias having dimensions of 10-25 mu m. After 1000 cycles of thermal shock from -65 to 150 degrees C, via chains showed no significant resistance change.>
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Cech et al. (1993) studied this question.
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