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August 19, 2026Polycyclic aromatic compounds

Synthesis and DFT Study of New Pyrano3,2-cQuinoline Derivatives for Antioxidant, Forensic, and Security Ink Applications

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Authors

EBEbtehal E. BahigRFR. FouadMIMostafa M. Ismail

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Overview

Experimental and computational study demonstrates tunable luminescent and antioxidant properties of novel pyrano[3,2-c]quinolines, highlighting forensic imaging and security ink utility.

Key Points

  • To synthesize novel pyrano[3,2-c]quinoline derivatives and evaluate their theoretical electronic structures, antioxidant capacity, and applications in forensic imaging and anticounterfeiting inks.
  • Synthesized pyrano[3,2-c]quinoline-2,5-dione derivatives via nucleophilic substitution and condensation reactions using 6-ethyl-4-chloropyrano[3,2-c]quinoline-3-carbaldehyde 2 with sulfur nucleophiles, primary amines, and active methylene compounds.
  • Performed DFT computations at the B3LYP/6–311++G(d,p) level to model geometrical structure, MEP, Fukui functions, FMO characteristics, and NMR properties.
  • Assessed antioxidant performance using the DPPH radical scavenging assay and characterized photoluminescent emission across varied substrates and ink preparations.
  • Compounds 4, 7, and 9 exhibited the highest DPPH radical scavenging activity among the series, though their scavenging potency was lower than that of ascorbic acid.
  • Compounds 5 (yellow–green) and 6 (gold–yellow) successfully resolved latent fingerprints with sharp ridge clarity across porous, nonporous, and multicolored substrates.
  • Luminescent ink formulations based on compounds 3 (green–yellow), 8 (blue), and 11 (violet) demonstrated stable, humidity-resistant emission suitable for secure data encoding.

Cite This Study

Bahig et al. (2026) studied this question.

synapsesocial.com/papers/6a8563eb03308d306e2d74e3https://doi.org/10.1080/10406638.2026.2716118
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