Shining a light on click chemistry: The use of UV-radiation as trigger signal provides a facile means to obtain spatial and temporal control over polymer conjugation reactions in addition to providing a further means of achieving orthogonality in click transformations. In the current contribution, UV-radiation was employed to induce a highly efficient Diels-Alder conjugation of polymeric building blocks via the photo-induced in situ formation of highly reactive cis-dienes from a 2-methylbenzophenone precursor.
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Gruendling et al. (2011) studied this question.
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