[Ag ₂ ([15]aneS ₅ ) ₂ ] ²⁺ : a binuclear silver( I ) complex incorporating asymmetrically bridging thioether donors. ([15]aneS ₅ = 1,4,7,10,13-pentathiacyclopentadecane)

Reaction of AgNO3 with [15]aneS5 affords the homoleptic, binuclear complex [Ag2([15]aneS5)2]2+ which shows [3 + 1] thioether co-ordination to one silver(I) centre and [4 + 1] thioether donation to the other, with one S-donor of each macrocycle bridging asymmetrically between the two metal centres.