Fluctuation theory of hydrogen bonding applied to vibration spectra of HOD molecules in liquid water. II. Infrared spectra: contour shape, integrated intensity, temperature dependence

The infrared spectra of HOD molecules in liquid water are calculated at constant density over the temperature range of 10 to 400°C from the statistical distributions of the vibration frequencies of water OH-groups determined previously from the experimental Raman spectra. Their shape and position are extrapolated over a wider temperature range. The dependence of contour shape and integrated intensity of the IR band on the frequency of its maximum, the first moment of a statistical contour and temperature are described numerically and analytically. Calculations are in qualitative agreement with all available experimental material and fitted quantitatively at a density of water of ∼1 g cm−3. The success of the proposed model applied to infrared spectra supports once more the continuum treatment of liquid water structure.