Facile assembly of hybrid materials containing polyoxometalate cluster anions and organic dyecations: crystal structures and initial spectral characterization

This is the authors' abstract. We don't add key points for this paper.

Salts of the pararosaniline dye cation and four polyoxometalate cluster anions have been isolated under both ambient and hydrothermal conditions; structural and initial spectroscopic data are consistent with significant perturbation of ion electronic states induced by charge-assisted N-H---O hydrogen bonds.