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The synthesis of MTW-type aluminosilicate zeolites in the absence of organic structure-directing agents (OSDAs) was successfully attained by the addition of calcined ZSM-12 seeds to (Li, Na)-aluminosilicate gels. In this system, Li cation plays a crucial role in the growth of the MTW crystals.
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Iyoki et al. (2010) studied this question.
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