A simple relation connecting the temperature shift, the recoil‐free fraction, and the force constant has been derived. The force constants for host–host and for impurity–host atoms and their ratios have been calculated from this relation. The values thus obtained are compared with the values obtained by other authors. The agreement has been found to be satisfactory and confirms the applicability of the derived relation. The results also indicate the change in the force constant for an impurity atom in a host lattice.
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Gupta et al. (1972) studied this question.
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