The structure and electronic properties of a series of Mn IV spinel oxides, with the general formula, AM 0.5 Mn 1.5 O 4 (A = Li, Cu; M = Ni, Mg), are investigated. These materials form an interesting analogy to pyrochlore structures that show colossal magnetoresistance properties. Studies of all the compounds show spontaneous magnetization at a well-defined transition temperature and their semiconducting nature.
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Branford et al. (2002) studied this question.
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