We report new calculations of the cooling rate of primordial gas by the HD molecule, taking into account its ro-vibrational structure. The HD cooling function is calculated including radiative and collisional transitions for J ≤ 8 rotational levels, and for the vibrational levels v= 0, 1, 2 and 3. The ro-vibrational level population is calculated from the balance equation assuming steady state. The cooling function is evaluated in the ranges of the kinetic temperatures, Tk, from 102 to 2 × 104 K and the number densities, nH, from 1 to 108 cm−3. We find that the inclusion of collisional ro-vibrational transitions increases significantly the HD cooling efficiency, in particular for high densities and temperatures. For nH≳ 105 and Tk∼ 104 K the cooling function becomes more than an order of magnitude higher than previously reported. We give also the HD cooling rate in the presence of the cosmic microwave radiation field for radiation temperatures of 30, 85 and 276 K (redshifts of 10, 30 and 100). The tabulated cooling functions are available at http://www.cifus.uson.mx/PersonalPages/anton/DATA/HDcooling/HDcool.html. We discuss the relevance to explore the effects of including our results into models and simulations of galaxy formation, especially in the regime when gas cools down from temperatures above ∼3000 K.
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